Remoción de negro de Eriocromo T de agua utilizando un material compuesto a base de quitosano/zeolita: un estudio cinético

A composite material was prepared using chitosan and chabazite for the removal of Eriochrome T black dye from water. Scanning electron microscopy (SEM) analyses showed chabazite particles embedded in the chitosan matrix. Thermogravimetric analyses indicated that chitosan degrades chemically at tempe...

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Autores principales: Guzmán Grijalva, Héctor Manuel, Alvarado Ibarra, Juana, Zamarrón Pulé, Martín Francisco, Esquer Peralta, Javier
Formáid: Online
Teanga:eng
Foilsithe: Universidad de Sonora 2021
Rochtain Ar Líne:https://biotecnia.unison.mx/index.php/biotecnia/article/view/1479
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Achoimre:A composite material was prepared using chitosan and chabazite for the removal of Eriochrome T black dye from water. Scanning electron microscopy (SEM) analyses showed chabazite particles embedded in the chitosan matrix. Thermogravimetric analyses indicated that chitosan degrades chemically at temperatures above 225 °C; chabazite only experiences weight decrease due to moisture loss. Fourier transform infrared spectroscopy (FTIR) analyses on chitosan detected the presence of O-H, N-H, C-H, C-N and C-O bonds, protonated amino groups and saccharides. In chabazite, H2O molecules, T-O and O-T-O groups, where “T” corresponds to Si or Al atoms, isolated H-bonded O-H groups, and Si-O-Si groups were detected. In kinetic experiments, an 86 % decrease of the dye concentration in solution was achieved in approximately 500 minutes. The linearization method was used to evaluate the fit of the experimental data with the pseudo-first-order, pseudo-second order, Elovich and intra-particle diffusion adsorption kinetic models. The kinetic experiments showed that the sorption mechanism corresponds to a pseudo-second order model.